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A group of Italian glazed terracotta sculptures, attributed to the della Robbia workshop of Florence, is partly displayed in the Louvre Museum. Analyses of the apparently homogeneous sculptures by techniques such as PIXE, SEM, ICP/AES and ICP/MS have identified differences in the materials used. The data provide a subdivision of the sculptures, which is compatible with what is known from historical documents and artistic considerations, and suggest a date for this ensemble at the end of the 15th century, when the della Robbia family was involved in the decoration of the San Frediano church in Florence.
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