Dating Archaeological Copper/Bronze Artifacts by Using the Voltammetry of Microparticles

Antonio Doménech‐Carbó · María Teresa Doménech‐Carbó · Sofia Capelo · Trinidad Pasíes Oviedo · Isabel Martínez‐Lázaro

52 citations0/0 files storedAngewandte Chemie International Edition

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Cultural Heritage Materials Analysis Corrosion Behavior and Inhibition Metallurgy and Cultural Artifacts

Abstract

A method for dating copper/bronze archaeological objects aged in atmospheric environments is proposed based on the specific signals for cuprite and tenorite corrosion products measured through the voltammtry of microparticles method. The tenorite/cuprite ratio increased with the corrosion time and fitted to a potential law that yielded a calibration curve usable for dating purposes.

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References

2003Catalogue of 45 reference Raman spectra of minerals concerning research in art history or archaeology, especially on corroded metals and coloured glass 2002Copper and Bronze in Art: Corrosion, Colorants, Conservation 2004Corrosion of iron archaeological artefacts in soil: characterisation of the corrosion system 2003Raman spectroscopy of selected copper minerals of significance in corrosion 1960Part I, The Development of the Method 2004XPS study of the atmospheric corrosion of copper alloys of archaeological interest 2009Electrochemical Methods in Archaeometry, Conservation and Restoration 2007Electrochemical identification of bronze corrosion products in archaeological artefacts. A case study

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