Article2012

Zinc white: a review of zinc oxide pigment properties and implications for stability in oil-based paintings

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Cultural Heritage Materials Analysis Conservation Techniques and Studies Pigment Synthesis and Properties

Abstract

Zinc oxide became a frequent component of 20th-century paints following its first commercial availability in the previous century. Aspects of zinc oxide pigment production and paint formulation which influence the reactive tendencies of zinc oxide in oil-based paints are reviewed. Particular attention is given to the formation and aggregation of zinc soaps which have been linked to deterioration in paintings. Pigment particle properties, fatty acid profiles, paint additives and environmental conditions are all significant factors.

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References

1979National Gallery Technical Bulletin 2007Analytical Imaging Studies of Cross-Sections of Paintings Affected by Lead Soap Aggregate Formation 2003The characterisation of lead fatty acid soaps in ‘protrusions’ in aged traditional oil paint 2006Kinetics of oil saponification by lead salts in ancient preparations of pharmaceutical lead plasters and painting lead mediums 2002The Artist's Assistant, Oil Painting Instruction Manuals and Handbooks in Britain 1800-1900 with Reference to Selected Eighteenth-Century Sources 1993Art in the Making: Impressionism

Cited by

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