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An "absolute" value for the molar volume of Si in Si single crystals is presented as 12.058 820 7(54) cm/sup 3/ mol/sup -1/ with a relative standard uncertainty of 4.5/spl middot/10/sup -7/. It is argued that the consistency of most of the molar volume determinations is useful for evaluating the quality of the Si single crystals involved. A value for the Avogadro constant is derived as 6.022 133 9(27)/spl middot/10/sup 23/ mol/sup -1/ having a relative standard uncertainty of 4.6/spl middot/10/sup -7/.
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