Article2010

Corroding glass, corroding metals: survey of joint metal/glass corrosion products on historic objects

21 citations0/0 files storedCorrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control

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Cultural Heritage Materials Analysis Conservation Techniques and Studies Building materials and conservation

Abstract

Corroding glass forms alkali(ne) surface films, which may lead to special metal corrosion products in the contact zone, for example different sodium copper carbonates or basic sodium lead carbonate. Sodium copper formate acetate was found on objects exposed to long term emissions from wood. A higher pH value may also lead to basic compounds, which normally do not form, e.g. the newly characterised Cu2(OH)3 HCOO. The alkaline films also create a reactive environment for the formation of formates from formaldehyde (e.g. emitted from glues) due to the Cannizzaro reaction or possibly from the neglected pollutant carbon monoxide. Further products containing, for example, potassium or sulphate may be expected.

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References

2002Copper and Bronze in Art: Corrosion, Colorants, Conservation 1973The Conservation of Antiquities and Works of Art 2009Alteration of soda silicate glasses by organic pollutants in museums: Mechanisms and kinetics 1955Chalconatronite: An Alteration Product on Some Ancient Egyptian Bronzes 2002The Characterization of a New Pale Blue Corrosion Product Found on Copper Alloy Artifacts 1989Characterization of corrosion products on old protective glass, especially daguerreotype cover glasses 1990Mineralogical changes arising from the use of aqueous sodium carbonate solutions for the treatment of archaeological copper objects

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2017When Glass and Metal Corrode Together, V: Sodium Copper Formate 2015Solid-State Structure of a Degradation Product Frequently Observed on Historic Metal Objects 2017Glass-Induced Lead Corrosion of Heritage Objects: Structural Characterization of K(OH)·2PbCO3 2022Curious Corrosion Compounds Caused by Contact: A Review of Glass-Induced Metal Corrosion on Museum Exhibits (GIMME)

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