The Unity of Chemistry and Physics: Absolute Reaction Rate Theory

Abstract

Henry Eyring's absolute rate theory explains the size of chemical reaction rate constants in terms of thermodynamics, statistical mechanics, and quantum chemistry. In addition it uses a number of unique concepts such as the 'transition state'. A key feature of the theory is that the explanation it provides relies on the comparison of reaction rate constant expressions derived from these individual theories. In this paper, the example is used to develop a naturalized notion of reduction and the unity of science. This characterization provides the necessary clues to the sort of inter-theoretic linkages that are present in the theory of reaction rates. The overall theory is then further characterized as a theory network, establishing connections between non-reductive notions of inter-theory connections. This characterization also sheds new light on the unity of science.

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