SURFACE‐ENRICHMENT OF BURIED METALS

E. T. Hall

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Cultural Heritage Materials Analysis Ancient and Medieval Archaeology Studies Metallurgy and Cultural Artifacts

Abstract

“Surface‐enrichment” is a term which is now commonly used to describe the composition changes which have taken place during the life of a buried noble metal alloy. In fact “surface depletion” might be a better term, since it seems likely that it is the leaching out of the less chemically stable elements which causes the surface composition to change. However, I have kept to the more frequently used term throughout the following discussion.

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2008Silver surface enrichment controlled by simultaneous RBS for reliable PIXE analysis of ancient coins 1986Some problems in analysing museum material by nondestructive surface sensitive techniques 1993Comparison of EDXRF and PIXE in the analysis of ancient gold coins 2010Non-destructive determination of the silver content in Roman coins (nummi), dated to 308–311 A.D., by the combined use of PIXE-alpha, XRF and DPAA techniques 1977X‐RAY FLUORESCENCE ANALYSIS OF ANCIENT GLASS: THE IMPORTANCE OF SAMPLE PREPARATION 2000X-ray Fluorescence Applications for the Study and Conservation of Cultural Heritage 2000The study of the characterisation and provenance of coins and other metalwork using XRF, PIXE and Activation Analysis 2020Non-destructive identification of surface enrichment and trace element fractionation in ancient silver coins

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