Article2015

Micro-XANES study on Mn browning: use of quantitative valence state maps

Gert Nuyts · Simone Cagno · Simone Bugani · Koen Henri Janssens

17 citations0/0 files storedJournal of Analytical Atomic Spectrometry

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Cultural Heritage Materials Analysis Electron and X-Ray Spectroscopy Techniques X-ray Spectroscopy and Fluorescence Analysis

Abstract

For the first time quantitative Mn valence state maps were obtained, by conversion of ratio maps I Mn(E1) / I Mn(E2) using a calibration curve, and were used in the evaluation of reducing treatments on historical glass suffering from Mn browning.

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References

1992Conservation of Glass 2005Archaeological glass alteration products in marine and land-based environments: morphological, chemical and microtextural characterization 2004Potassium–Calcium Glass: New Data and Experiments*2006Leaching studies on naturally weathered potash-lime–silica glasses 2006A Study on Corrosion Processes of Archaeological Glass from the Valencian Region (Spain) and its Consolidation Treatment 2004Statistical evaluation of potash-lime-silica glass weathering 2010MANGANESE STAINING OF ARCHAEOLOGICAL GLASS: THE CHARACTERIZATION OF Mn-RICH INCLUSIONS IN LEACHED LAYERS AND A HYPOTHESIS OF ITS FORMATION 1999Characterisation of surface layers formed under natural environmental conditions on medieval stained glass and ancient copper alloys using SEM, SIMS and atomic force microscopy

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