Articlegreen2013

Nanoscale Investigation of the Degradation Mechanism of a Historical Chrome Yellow Paint by Quantitative Electron Energy Loss spectroscopy Mapping of Chromium Species

Haiyan Tan · He Tian · Johan Verbeeck · Letizia Monico · Koen Henri Janssens · Gustaaf Van TENDELOO

40 citations0/0 files storedAngewandte Chemie International Edition

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Cultural Heritage Materials Analysis Electron and X-Ray Spectroscopy Techniques Advanced Electron Microscopy Techniques and Applications

Abstract

Getting the picture: The investigation of 100 year old chrome yellow paint by transmission electron microscopy and spectroscopy has led to the identification of four types of core-shell particles. This nanoscale investigation has allowed a mechanism to be proposed for the darkening of some bright yellow colors in Van Gogh's paintings (e.g. in Falling leaves (Les Alyscamps), 1888).

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References

2011Degradation Process of Lead Chromate in Paintings by Vincent van Gogh Studied by Means of Synchrotron X-ray Spectromicroscopy and Related Methods. 2. Original Paint Layer Samples 2011Degradation Process of Lead Chromate in Paintings by Vincent van Gogh Studied by Means of Synchrotron X-ray Spectromicroscopy and Related Methods. 1. Artificially Aged Model Samples 2012Degradation Process of Lead Chromate in Paintings by Vincent van Gogh Studied by Means of Spectromicroscopic Methods. 3. Synthesis, Characterization, and Detection of Different Crystal Forms of the Chrome Yellow Pigment 2012Degradation Process of Lead Chromate in Paintings by Vincent van Gogh Studied by Means of Spectromicroscopic Methods. 4. Artificial Aging of Model Samples of Co-Precipitates of Lead Chromate and Lead Sulfate 2013High-resolution fluorescence mapping of impurities in historical zinc oxide pigments: hard X-ray nanoprobe applications to the paints of Pablo Picasso

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2018Chemical Mapping by Macroscopic X‐ray Powder Diffraction (MA‐XRPD) of Van Gogh's Sunflowers: Identification of Areas with Higher Degradation Risk 2017Beyond the color: A structural insight to eosin-based lakes 2021Nanoscale Analysis of Historical Paintings by Means of O‐PTIR Spectroscopy: The Identification of the Organic Particles in L′Arlésienne (Portrait of Madame Ginoux) by Van Gogh 2018A little key to oxalate formation in oil paints: protective patina or chemical reactor?2016

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