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Elemental and Molecular Segregation in Oil Paintings due to Lead Soap Degradation

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References

1997Raman spectroscopic library of natural and synthetic pigments (pre- ≈ 1850 AD)992 cited
1979National Gallery Technical Bulletin346 cited
2003The Characterization of Metal Soaps249 cited
2014Characterisation of metal carboxylates by Raman and infrared spectroscopy in works of art237 cited
2008Attenuated total reflection micro FTIR characterisation of pigment–binder interaction in reconstructed paint films214 cited
2015An infrared spectroscopic study of the nature of zinc carboxylates in oil paintings150 cited
2007Analytical Imaging Studies of Cross-Sections of Paintings Affected by Lead Soap Aggregate Formation129 cited
2008ATR-FTIR imaging for the analysis of organic materials in paint cross sections: case studies on paint samples from the National Gallery, London127 cited
2003The characterisation of lead fatty acid soaps in ‘protrusions’ in aged traditional oil paint120 cited
2006Kinetics of oil saponification by lead salts in ancient preparations of pharmaceutical lead plasters and painting lead mediums101 cited
2012Metal Stearate Distributions in Modern Artists' Oil Paints: Surface and Cross-Sectional Investigation of Reference Paint Films Using Conventional and Synchrotron Infrared Microspectroscopy92 cited
2007Micro-analytical study of interactions between oil and lead compounds in paintings90 cited
2016The crystallization of metal soaps and fatty acids in oil paint model systems

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80 cited

2005Binding medium, pigments and metal soaps characterised and localised in paint cross-sections64 cited

2011SEM Backscattered-Electron Images of Paint Cross Sections as Information Source for the Presence of the Lead White Pigment and Lead-Related Degradation and Migration Phenomena in Oil Paintings63 cited

2008Evaluation of the “added value” of SIMS: A mass spectrometric and spectroscopic study of an unusual Naples yellow oil paint reconstruction40 cited

Cited by

2019Unravelling the spatial dependency of the complex solid-state chemistry of Pb in a paint micro-sample from Rembrandt's Homer using XRD-CT27 cited
2020Zinc oxide instability in drying oil paint24 cited
2021Time‐of‐flight secondary ion mass spectrometry imaging in cultural heritage: A focus on old paintings24 cited
2017Time-Resolved Photoluminescence Microscopy for the Analysis of Semiconductor-Based Paint Layers23 cited
2023Correlated x-ray fluorescence and ptychographic nano-tomography on Rembrandt’s The Night Watch reveals unknown lead “layer”20 cited
2025Advanced X-ray techniques to study the alteration of pigments in paintings17 cited
2018On the photoluminescence changes induced by ageing processes on zinc white paints17 cited
2019Investigation of mineralization products of lead soaps in a late medieval panel painting17 cited
2019Revealing the Distribution of Metal Carboxylates in Oil Paint from the Micro‐ to Nanoscale16 cited
2020Review of the use of NMR spectroscopy to investigate structure, reactivity, and dynamics of lead soap formation in paintings15 cited
2022Chemo-mechanical model for degradation of oil paintings by amorphous and crystalline metal soaps11 cited