Acides amines et acides gras sur un même chromatogramme: un autre regard sur l'analyse des liants en peinture

Witold Nowik

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Cultural Heritage Materials Analysis Historical Art and Architecture Studies Analytical Chemistry and Chromatography

Abstract

The method presented in this article permits rapid analysis of the composition of proteinaceous and fatty painting media. It is possible to obtain the volatile derivatives of anlino and fatty acids in a few seconds, at room temperature and in the presence of water; their separation takes only a few minutes. Using this method it is possible to record the amino acid and fatty acid chromatograms simultaneously. Analytical results are presented for proteinaceous media such as cows' milk, casein, egg white and yolk, gelatine, and for fatty media such as linseed, walnut and poppyseed oil. Each type of medium can be identified from the information in the relevant chromatogram, and it may be possible to develop a method for the analysis of mixed media, for example tempera.

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References

1966The Gas Chromatographic Examination of Paint Media. Part I. Fatty Acid Composition and Identification of Dried Oil Films 1978Conservation and Restoration of Pictorial Art 1972Conservation of paintings and the graphic arts

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